Draw both organic products of the following reaction. Hint:There will be two deuterium atoms in the…
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Question “Draw both organic products of the following reaction. Hint:There will be two deuterium atoms in the…”
Draw both organic products of the following reaction.
Hint:There
will be two deuterium atoms in the benzyl alcohol
product.
Answer
The reaction of an ester is given with \rmLiAl\rmD_4
Esters on reaction with \rmLiAl\rmD_4
This is the intermediate aldehyde that was formed:
An asterisk indicates that it is an intermediate.
Further reductions of aldehyde are made and the first product is:
The proton is also formed by the ethoxide-ion in the previous step. Thus, the second product looks like this:
Ans:
These are the products of the above reaction:
Conclusion
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